粉尘爆炸反应工程学简要综述

１９９３年在波兰召开的第五届国际粉尘爆炸学术会议上，邓煦帆曾在论文中提议建立粉尘爆炸反应工程学，并提出学科的目的意义、性质、主要组成部分和研究方法。本文拟将国内外有关本学科范围内的贡献，加以简要综述，以期能逐渐形成本学科的自身体系和特点。     

C6H12N4+Mg+KClO4+SrSO4系统的振荡控制和安全分析

从实验和数值分析两方面研究了C6Hl2N 4+Mg+KClO4+SrSO4反应系统的振荡燃烧现象,并对反应机理进行了深层次的分析.结果表明,振荡燃烧是由化学动力学的非线性反馈引起的,即:反应系统中镁的三相与氧气的相互竞争反应造成系统的非线性化学振荡燃烧.氧化剂和可燃剂的比值,以及频率调节剂等吸热物质可调节气相镁的生成速率,能有效地控制药剂的振荡频率.选取适当的控制参数,可以使反应按照预定的、安全的过程进行,避免爆燃的产生.本文的研究结果对化工、军事等领域的安全控制具有重要意义.     

大气中SO2的液相氧化研究

大气中ＳＯ２液相氧化是形成酸雨的重要途径，降雨中含有各种无机离子和有机物质，它们可能催化或抑制液相氧化反应的进行。本文根据四川酸雨样品组成，进行了ＳＯ２在模拟雨水及实际雨水中的氧化实验，考查了Ｖ，Ｆｅ，Ｍｎ等离子对ＳＯ２氧化的催化作用，Ｈ２Ｏ２对ＳＯ２的氧化以及降水中有机物质甲醛对各反应的影响。实验结果为了解酸雨的成固，研究酸雨控制对策提供了科学依据。     

Miscibility and Biodegradability of Poly(Butylene Succinate)/Poly(Butylene Terephthalate) Blends

As one of the biodegradable polymers, the blend of poly(butylene succinate) and poly(butylene terephthalate) is dealt with in this study. In our previous work, it was demonstrated that PBS and PBT are immiscible not only from the changes of T _g but also from logG–log G plots. It is expected that the biodegradability of the blends could be improved by enhancing the miscibility. We tried to induce the transesterification reaction between two polyesters with various time intervals to enhance the miscibility of the blends. The extent of transesterification reaction was examined by ¹H-NMR. We utilized a dynamic mechanical thermal analyzer and a rotational rheometer to investigate the changes in miscibility. We also verified the biodegradability of PBS/PBT blends after the transesterification reaction by the composting method.     

Fe-pillared clay as a Fenton-type heterogeneous catalyst for cinnamic acid degradation

Fe-pillared montmorillonite has been used as a Fenton-type heterogeneous catalyst for the removal of cinnamic acid in water. The influences of the cinnamic acid, catalyst and H2O2 concentrations and pH on the removal rate of cinnamic acid have been studied. The results show that the efficiency of Fe-pillared montmorillonite is higher than that of the Fe ions in the homogeneous phase, and less sensitive to pH.     

Point Sampling Digital Imagery with ‘Samplepoint’

Measuring percent occurrence of objects from digital images can save time and expense relative to conventional field measurements. However, the accuracy of image analysis had, until now, not reached the level of the best conventional field measurements. Additionally, most image-analysis software programs require advanced user training to successfully analyze images. Here we present a new software program, ‘SamplePoint,’ that provides the user a single-pixel sample point and the ability to view and identify the pixel context. We found SamplePoint to allow accuracy comparable with the most accurate field-methods for ground-cover measurements. Expert use of the program requires minimal training and its ease of use allows rapid measurements from image data. We recommend SamplePoint for calibrating the threshold-detection level of image-analysis software or for making direct measurements of percent occurrence from digital images.     

近场地震作用下框架结构的损伤机理

首先讨论了近场地面运动的特征及各种抗震规范对近场地震的设防，然后采用非线性时程分析方法，对一个10层框架结构在近场地震作用下的响应特性进行了研究。同时对该框架结构进行了Pushover分析，通过与非线性时程分析结果进行对比，说明Pushover分析方法不能正确评估结构在近场地震作用下的抗震性能。     

铁炭复配修复地下水中NO_3~--N的条件研究

采用了铁炭复配修复地下水中NO3--N,探讨了实验条件对修复效果的影响。结果表明,在pH值近中性条件(初始pH 6.42)下,反应时间为1 h时NO3--N修复率达到60.85%;Fe/C=1∶1时介质最佳用量分别为4~5 g;Fe/C=1/1.5时修复率为72.80%;反应速率在高振荡强度下大于低振荡强度;氧化铜的催化效果最好,可使修复率提高7.5个百分点。铁炭复配介质修复地下水中NO3--N是有效可行的,修复率随反应时间的增加而提高,在Fe/C=1∶1时修复率与介质用量呈正相关,无限减小Fe/C比并不能无限提高修复率,振荡强度对修复具有显著影响,低振荡强度下的修复过程较高强度存在滞后现象,并非所有金属氧化物催化剂对铁炭修复NO3--N均有促进作用。     

重型自卸汽车车架横梁异常断裂原因分析

针对无副车架的重型自卸汽车在使用过程中出现的车架横梁异常断裂问题,建立了以板壳单元为基本单元的自卸汽车车架有限元分析模型,采用NASTRAN有限元分析软件对车架强度进行分析.有限元分析结果表明,车架横梁异常断裂现象是横梁连接部位应力值大于材料的屈服强度引起的,这与实车车架断裂结果吻合.根据实际工艺要求,改造车架结构,将连接第2根横梁和纵梁的L板厚度变大,并将平衡悬架推力杆支座由整体式支撑改为分体式支撑,从而使两处的最大应力值分别比原结构下降20.4%和51.7%.改进后车架断裂区的强度明显提高,这表明改造方法有效.     

安全生产支撑模式及架构探讨

用系统论方法分析安全生产工作的整体性概念,指出安全生产支撑体系构建应以系统论的科学理论为基础,并提出在社会主义市场经济条件下,制度支撑、组织支撑和技术支撑共同构成稳定完整的安全生产支撑模式。在架构上,安全生产支撑体系可细分为若干各具特点的服务与支持系统,包括法律法规、安全标准、政策措施、企业安全管理、政府安全监管、事故应急管理、科技创新、中介服务、宣传教育等体系,该体系相对独立、相互联系,共同构成完整的安全生产支撑体系框架。